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A textbook of inorganic chemistry vol.VI part II Phosphorus by Prideaux Edmund BR

By Prideaux Edmund BR

Illustrated, disguise no longer so solid / omslag onfris, foxing / roestvlekjes / / Chemistry / Engels / English / Anglais / Englisch / difficult disguise / sixteen x 23 cm / 238 .pp /

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It resembles the reactions with alkyl halides and may result in an "amphoteric" hydride: L4Ni + H+ → L4HNi+ The starting material is an 18 electron nickel zero complex which is protonated forming a divalent nickel hydride. This can react further with alkenes to give alkyl groups, but it also reacts as an acid with hard bases to regenerate the nickel zero complex. Similar oxidative addition reactions have been recorded for phenols, water, amines, carboxylic acids, mineral acids (HCN), etc. Oxidative additions involving C-H bond breaking have recently been the topic of an extensive study, usually referred to as C-H activation; the idea is that the M-H and M-hydrocarbyl bonds formed will be much more prone to functionalization than the unreactive C-H bond.

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